The reactivity of antimony and bismuth<i>N</i>,<i>C</i>,<i>N</i>-pincer compounds toward K[BEt<sub>3</sub>H] – the formation of heterocyclic compounds<i>vs</i>. element–element bonds<i>vs.</i>stable terminal Sb–H bonds
Pavel Novák, Milan Erben, Roman Jambor, Martin Hejda, Aleš Růžička, Elena Rychagova, Sergey Yu. Ketkov, Libor Dostál
Abstract
9-Sb, Me 10-Sb) could be isolated instead. Nevertheless, heating of both 9-Sb and 10-Sb led to an activation of a labile Sb-H bond and the formation of distibines 7/8-Sb.
Topics & Concepts
PnictogenReactivity (psychology)AntimonyBismuthChemistryMedicinal chemistryStereochemistryHydrideCrystallographyMetalInorganic chemistryOrganic chemistryPhysicsMedicineQuantum mechanicsAlternative medicinePathologySuperconductivitySynthesis and characterization of novel inorganic/organometallic compoundsOrganoboron and organosilicon chemistryCoordination Chemistry and Organometallics