Stereodivergent asymmetric synthesis of P-atropisomeric Si-stereogenic monohydrosilanes
Bo Yang, Xing-Fa Tan, Yicong Ge, Yingzi Li, Chuan He
Abstract
We herein report an efficient one-pot strategy for the stereodivergent asymmetric synthesis of various P-atropisomeric Si-stereogenic monohydrosilanes with excellent stereoselectivity from dichlorosilanes.
Topics & Concepts
StereocenterChemistryStereoselectivityAtropisomerStereochemistryCombinatorial chemistryEnantioselective synthesisOrganic chemistryCatalysisOrganoboron and organosilicon chemistryAxial and Atropisomeric Chirality SynthesisCatalytic Cross-Coupling Reactions