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Co‐MOF Nanosheet Arrays for Efficient Alkaline Oxygen Evolution Electrocatalysis

Yu Jin, Yang Cao, Qian Liu, Yonglan Luo, Yang Liu, Xifeng Shi, Abdullah M. Asiri, Tingshuai Li, Xuping Sun

2021ChemNanoMat48 citationsDOI

Abstract

Abstract It's highly desirable to devise and develop non‐precious metal catalysts for efficient water oxidation catalysis in alkaline solution. Herein, we report Co‐MOF nanosheet arrays grown on the three dimensional conductive nickel foam (Co‐MOF/NF) through a hydro‐thermal process for efficient alkaline oxygen evolution electrocatalysis. Such catalyst displays an excellent electrochemical performance by achieving an overpotential of 290 mV at 20 mA cm −2 in 1.0 M KOH. Besides, it possesses both a good electrochemical stability and a high turnover frequency of 0.14 s −1 at the overpotential of 400 mV.

Topics & Concepts

OverpotentialNanosheetElectrocatalystOxygen evolutionCatalysisElectrochemistryMaterials scienceChemical engineeringNickelInorganic chemistryChemistryNanotechnologyElectrodeMetallurgyOrganic chemistryEngineeringPhysical chemistryElectrocatalysts for Energy ConversionFuel Cells and Related MaterialsAdvanced battery technologies research