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Anisotropic thermo-mechanical response of layered hexagonal boron nitride and black phosphorus: application as a simultaneous pressure and temperature sensor

Hermann Muhammad, Mohamed Mézouar, Gastón Garbarino, Tomasz Porȩba, Giorgia Confalonieri, Matteo Ceppatelli, Manuel Serrano‐Ruiz, Maurizio Peruzzini, F. Datchi

2024Nanoscale10 citationsDOIOpen Access PDF

Abstract

high-temperature and high-pressure high-resolution synchrotron X-ray diffraction. In particular, we have quantitatively determined the subtle variations of the in-plane and volumetric thermal expansion coefficients and compressibility parameters by subjecting these materials to hydrostatic conditions and by collecting a large number of data points in small pressure and temperature increments. In addition, based on the anisotropic behavior of bP, we propose the use of this material as a sensor for the simultaneous determination of pressure and temperature in the range of 0-5 GPa and 298-1700 K, respectively.

Topics & Concepts

Hexagonal boron nitrideAnisotropyMaterials scienceBlack phosphorusBoronPhosphorusBoron nitrideDiffractionNitrideThermalHexagonal crystal systemComposite materialOptoelectronicsNanotechnologyCrystallographyMetallurgyOpticsLayer (electronics)ThermodynamicsChemistryPhysicsGrapheneOrganic chemistry2D Materials and ApplicationsBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials