Additive-free selective oxidation of aromatic alcohols with molecular oxygen catalyzed by a mixed-valence polyoxovanadate-based metal–organic framework
Hongrui Tian, Run‐Han Li, Jun Miao, Shuxia Liu, Fengfeng Wang, Zhiping Zheng
Abstract
A mixed-valence polyoxovanadate-based cadmium organic framework was synthesized and used as a recyclable catalyst for the high-yield additive-free selective oxidation of aromatic alcohols with molecular oxygen to their corresponding aldehydes.
Topics & Concepts
ChemistryCatalysisValence (chemistry)PolyoxometalateAlcohol oxidationAldehydeSelectivityBond cleavageOxygenDensity functional theoryMetal-organic frameworkMetalCombinatorial chemistryOrganic chemistryComputational chemistryAdsorptionPolyoxometalates: Synthesis and ApplicationsOxidative Organic Chemistry ReactionsMetal-Organic Frameworks: Synthesis and Applications