Metal-free 3D donor–acceptor COF with low exciton binding for solar fuel production based on CO<sub>2</sub>reduction
Anupam Dey, Faruk Ahamed Rahimi, Soumitra Barman, Arpan Hazra, Tapas Kumar Maji
Abstract
A donor–acceptor based 3D TT-COF is employed as a metal-free photocatalyst for CO 2 reduction. TT-COF selectively produces CO from CO 2 using visible light, without external photosensitizers or cocatalysts by minimizing exciton binding energy.
Topics & Concepts
AcceptorExcitonPhotochemistryMetalMaterials scienceSolar fuelBinding energyPhotocatalysisVisible spectrumReduction (mathematics)ChemistryOptoelectronicsCatalysisOrganic chemistryMetallurgyPhysicsAtomic physicsQuantum mechanicsCondensed matter physicsMathematicsGeometryAdvanced Photocatalysis TechniquesCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and Applications