[BO<sub>2</sub>]<sup>−</sup> as a Synthon for the Generation of Boron‐Centered Carbamate and Carboxylate Isosteres
Anne‐Frédérique Pécharman, Michael S. Hill, Claire L. McMullin, Mary F. Mahon
Abstract
Abstract Oxoborane carbamate and carboxylate analogues result from the in situ trapping of [BO 2 ] − produced by elimination of 2,3‐dimethyl‐2‐butene from a pinacolatoboryl anion.
Topics & Concepts
SynthonCarboxylateBoronCarbamateChemistryStereochemistryMedicinal chemistryOrganic chemistryOrganoboron and organosilicon chemistryBoron Compounds in ChemistryCrystallography and molecular interactions