SO<sub>4</sub><sup>2−</sup> ions as a nucleophilic reagent: straightforward electrochemical access to organosulfates
Chen Li, Zhuo Chen, Xue-Yang Guo, Li‐Rong Wen, Ming Li, Lin‐Bao Zhang
Abstract
An electrooxidation direct difunctionalization of alkynes with sulfonyl hydrazides has been developed for the construction of sulfonyl alkenyl sulfates in the absence of metal catalysts and a stoichiometric amount of oxidants.
Topics & Concepts
NucleophileReagentSulfonylChemistryElectrochemistryStoichiometryIonCatalysisInorganic chemistryCombinatorial chemistryOrganic chemistryPhysical chemistryElectrodeAlkylSulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsRadical Photochemical Reactions