Tailored design, synthesis, and catalytic aspects of mononuclear <i>cis</i>-dichloro copper(<scp>ii</scp>) complexes with simple DPA-derived tridentate ligands and their biomimicking activities
Arabinda Muley, Kalai Selvan Karumban, Sadananda Kumbhakar, Shobhit Mathur, Indrajit Roy, Anushka Verma, Manoj Kumar Kumawat, Somnath Maji
Abstract
Two new mononuclear pentacoordinated square pyramidal Cu( ii ) complexes with dipicolylamine-based tuned tridentate ligands have been prepared. Under aerobic conditions, o -aminophenol and catechol oxidation activities resulted in high turnover numbers.
Topics & Concepts
ChemistryCopperSimple (philosophy)CatalysisCombinatorial chemistryOrganic chemistryEpistemologyPhilosophyMetal complexes synthesis and propertiesAsymmetric Hydrogenation and Catalysis