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Understanding the Resistive Switching Behaviors of Top Electrode (Au, Cu, and Al)-Dependent TiO<sub>2</sub>-Based Memristive Devices

Yantao Yu, Zizhao Ding, Yaoying Ren, Xiangfei Wang, Hongguang Quan, Hong Jia, Chao Jiang

2024ACS Omega15 citationsDOIOpen Access PDF

Abstract

High Resolution Image Download MS PowerPoint Slide Memristor-based neuromorphic computing is promising toward their potential application of handling complex parallel tasks in the period of big data. To implement brain-inspired applications of spiking neural networks, new physical architecture designs are needed. Here, a serial memristive structure (SMS) consisting of memristive devices with different top electrodes is proposed. Top electrodes Au, Cu, and Al are selected for nitrogen-doped TiO 2 nanorod array-based memristive devices. The typical I – V cycles, retention, on/off ratio, and variations of cycle to cycle of top electrode-dependent memristive devices have been studied. Devices with Cu and Al electrodes exhibit a retention of over 10 4 s. And the resistance states of the device with the Al top electrode are reliable. Furthermore, the conductive mechanism underlining the I – V curves is discussed in detail. The interface-type mechanism and block conductance mechanism are illustrated, which are related to electron migration and ion/anion migration, respectively. Finally, the SMS has been constructed using memristive devices with Al and Cu top electrodes, which can mimic the spiking pulse-dependent plasticity of a synapse and a neuron body. The SMS provides a new approach to implement a fundamental physical unit for neuromorphic computing.

Topics & Concepts

ElectrodeMaterials scienceMemristorOptoelectronicsNanotechnologyResistive touchscreenElectrical engineeringChemistryEngineeringPhysical chemistryAdvanced Memory and Neural ComputingNeuroscience and Neural EngineeringCCD and CMOS Imaging Sensors