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Near-Infrared Light Induced Dynamic Structural Color Change of Amorphous Photonic Hydrogel

Yongqing Xia, Shuai Gao, Ronghua Yu, Zhujun Zeng, Hua He, Xiaohan Zhou, Ying Hu, Meiwen Cao, Shengjie Wang

2021ACS Applied Polymer Materials26 citationsDOI

Abstract

Light-induced photonic systems are rare in nature and usually lack a full color response in artificial systems. Herein, we first report a near-infrared (NIR) light controlled optical hydrogel; its structural color covers the full visible spectrum range. The hydrogel was fabricated by embedding dry thermoresponsive microgels film into a thermoresponsive hydrogel. Under the synergistic effect of the microgels and hydrogel, the hydrogel displayed a dynamic color with temperature changing, and it was reversible. Moreover, the structural colors were angle independent for the amorphous microgel arrays. When carbon nanotubes were integrated into the matrix hydrogel, dynamic structural colors can be displayed under NIR irradiation. Such NIR light-responsive photonic hydrogel film may provide potential applications in artificial skin, the military, and other fields.

Topics & Concepts

Structural colorationMaterials sciencePhotonicsAmorphous solidSelf-healing hydrogelsOptoelectronicsInfraredVisible spectrumPhotonic crystalNanotechnologyOpticsChemistryPolymer chemistryPhysicsOrganic chemistryPhotonic Crystals and ApplicationsPolydiacetylene-based materials and applicationsLiquid Crystal Research Advancements