Terminal-fluoride-coordinated air-stable chiral dysprosium single-molecule magnets
Jinjiang Wu, Guo‐Lu Wang, Zhenhua Zhu, Chen Zhao, Xiaolei Li, Yi‐Quan Zhang, Jinkui Tang
Abstract
Terminal fluoride ligands generate strong magnetic anisotropy in air-stable chiral dysprosium enantiomers supported by a bulky equatorial macrocycle, exhibiting a typical zero-field single-molecule magnet behaviour.
Topics & Concepts
DysprosiumFluorideTerminal (telecommunication)MoleculeMagnetMaterials scienceChemistryCrystallographyInorganic chemistryOrganic chemistryPhysicsTelecommunicationsQuantum mechanicsComputer scienceMagnetism in coordination complexesLanthanide and Transition Metal ComplexesPorphyrin and Phthalocyanine Chemistry