Structure, hydrogen bond dynamics and phase transition in a model ionic liquid electrolyte
Alexander E. Khudozhitkov, Peter Stange, Alexander G. Stepanov, Daniil I. Kolokolov, Ralf Ludwig
Abstract
The N–D bonds of triethylammonium cations in protic ionic liquids jump between equally populated sites. The librational angles increase with the interaction strength of the anions from strong to weak.
Topics & Concepts
Ionic liquidChemistryHydrogen bondPhysical chemistryIonIonic bondingEnthalpyRelaxation (psychology)Phase transitionPhase (matter)Chemical physicsComputational chemistryInorganic chemistryCrystallographyThermodynamicsMoleculeOrganic chemistryCatalysisPhysicsSocial psychologyPsychologyIonic liquids properties and applicationsAdvanced Battery Materials and TechnologiesSolid-state spectroscopy and crystallography