Luminescence properties of color-tunable YNbO<sub>4</sub>: Dy<sup>3+</sup>, Tm<sup>3+</sup> phosphors
Xin Wang, Xiangping Li, Sai Xu, Lihong Cheng, Jiashi Sun, Jinsu Zhang, Xizhen Zhang, Baojiu Chen
Abstract
Usually, Dy3+ doped phosphors can simultaneously generate both blue and yellow emissions which can be mixed as white light if the intensities of them are closer. The aim of this work is to explore white-light generation in Dy3+ doped YNbO4 phosphors by introducing Tm3+ to compensate the lack of blue component of Dy3+. To this end, the Dy3+, Tm3+ single- and co-doped YNbO4 phosphors were synthesized via a high-temperature solid-state reaction method. Under the excitation of 354 nm, the YNbO4: Dy3+ phosphors exhibit a blue emission at 487 nm and a yellow emission at 579 nm and the results indicated that the white light cannot be obtained from Dy3+ single-doped YNbO4 phosphors owing to the deficiency of blue spectral component. To tune the emission color, Tm3+ was introduced into Dy3+ doped samples, and the energy transfer behavior between Tm3+ and Dy3+ was investigated based on the fluorescence dynamics. The chromatic property of the while light emitting phosphor was studied. High-quality white emission was obtained when Tm3+ concentration was 1.0 mol%. The color coordinates and the correlated color temperature for the concentration-optimized sample are (0.3355, 0.3345) and 5352 K, respectively.