Trends in trigonal prismatic Ln-[1]ferrocenophane complexes and discovery of a Ho<sup>3+</sup>single-molecule magnet
Trevor P. Latendresse, Veacheslav Vieru, Apoorva Upadhyay, Nattamai S. P. Bhuvanesh, Liviu F. Chibotaru, Michael Nippe
Abstract
Lanthanide ferrocenophanes are an intriguing class of organometallic complexes that feature rare six-coordinate trigonal prismatic coordination environments of 4f elements with close intramolecular proximity to iron ions.
Topics & Concepts
Trigonal prismatic molecular geometryTrigonal crystal systemLanthanideIntramolecular forceSingle-molecule magnetMagnetCrystallographyChemistryIonMoleculeStereochemistryCrystal structurePhysicsMagnetic fieldMagnetizationOrganic chemistryQuantum mechanicsOctahedronMagnetism in coordination complexesLanthanide and Transition Metal ComplexesAdvanced NMR Techniques and Applications