Ru Single Atoms Anchored on Co<sub>3</sub>O<sub>4</sub> Nanorods for Efficient Overall Water Splitting under pH‐Universal Conditions
Yongfang Zhou, Yu Mao, Cuizhu Ye, Ziyun Wang, Shanghai Wei, J. Kennedy, Yufei Zhao, Hui Yang, Bruce C. C. Cowie, Geoffrey I. N. Waterhouse
Abstract
Abstract Single‐atom catalysts (SACs) show great promise for electrocatalytic water splitting due to their exceptional metal atom utilization efficiency. Herein, it is demonstrated that Ru single atoms (SAs) anchored on Co 3 O 4 nanorod arrays (Ru x ‐Co 3 O 4 , where x is the Ru loading in weight percent) afford outstanding electrocatalytic performance and durability for the oxygen evolution reaction (OER), hydrogen evolution reaction (HER), and overall water splitting across a wide pH range (0.3–14). Ru 8% ‐Co 3 O 4 achieves 10 mA cm⁻ 2 at overpotentials of only 214, 286, and 138 mV for OER, and 13, 72, and 59 mV for HER, in 1 m KOH, 0.1 m PBS, and 0.5 m H 2 SO 4 , respectively, outperforming benchmark RuO 2 and Pt/C catalysts. When Ru 8% ‐Co 3 O 4 is utilized as the anode and cathode catalysts in an anion exchange membrane water electrolyzer (AEMWE), a cell voltage of only 2.06 V is required to achieve 1 A cm⁻ 2 . Chronopotentiometry verified Ru 8% ‐Co 3 O 4 possesses excellent stability during both OER and HER at 100 mA cm⁻ 2 in acidic, neutral, and alkaline media. Density functional theory (DFT) calculations reveal that the abundant Ru‐O‐Co interfaces in Ru 8% ‐Co 3 O 4 shift the d‐band center from −1.72 eV (for Ru cluster/Co 3 O 4 ) to −1.58 eV (for Ru SA/Co 3 O 4 ), creating more energetically favorable pathways for OER and HER.