A highly stable Zn<sub>9</sub>-pyrazolate metal–organic framework with metallosalen ligands as a carbon dioxide cycloaddition catalyst
Fa‐Xue Ma, Fu‐Qi Mi, Meng-Jiao Sun, Tao Huang, Zian Wang, Teng Zhang, Rong Cao
Abstract
A three-dimensional (3D) metal–organic framework constructed from unprecedented Zn 9 O 2 (OH) 2 (pyz) 12 (pyz = pyrazolate) clusters and Ni(salen)-derived linkers was reported.
Topics & Concepts
CycloadditionCatalysisCarbon dioxideMetalChemistryMaterials scienceInorganic chemistryOrganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsCarbon dioxide utilization in catalysisCovalent Organic Framework Applications