Aggregation-Induced Emission with Alkynylcoumarin Dinuclear Gold(I) Complexes: Photophysical, Dynamic Light Scattering, and Time-Dependent Density Functional Theory Studies
Carla Cunha, Andrea Pinto, Adelino M. Galvão, Laura Rodrı́guez, J. Sérgio Seixas de Melo
Abstract
both anti. From time-resolved fluorescence experiments, the augment in the contribution of the longer decay component is found to be associated with the emission of the aggregate (AIE effect) and its nature (involving a dimer) rationalized from TDDFT electronic calculations.
Topics & Concepts
Time-dependent density functional theoryChemistryDimerDensity functional theoryFluorescencePhotochemistryLuminescenceAcetonitrileAggregation-induced emissionComputational chemistryOrganic chemistryOptoelectronicsPhysicsQuantum mechanicsNanocluster Synthesis and ApplicationsLuminescence and Fluorescent MaterialsOrganic Light-Emitting Diodes Research