Palladium-catalysed C–F alumination of fluorobenzenes: mechanistic diversity and origin of selectivity
Feriel Rekhroukh, Wenyi Chen, Ryan K. Brown, Andrew J. P. White, Mark R. Crimmin
Abstract
. In this instance, the kinetic C-H alumination intermediate could be isolated. Under catalytic conditions this intermediate converts to the thermodynamic C-F alumination product.
Topics & Concepts
PalladiumCatalysisSelectivityReagentChemistryHeterogeneous catalysisAluminiumOrganic chemistryFluorine in Organic ChemistryCatalytic Cross-Coupling ReactionsCoordination Chemistry and Organometallics