The O/S heteroatom effects of covalent triazine frameworks for photocatalytic hydrogen evolution
Manying Liu, Kangni Yang, Zhenyang Li, Erchuang Fan, Huafeng Fu, Like Zhang, Yange Zhang, Zhi Zheng
Abstract
, which is about 5.6 times that of CTF-8. Due to their low electronegativity, sulfur heteroatoms are more favorable for charge separation than oxygen heteroatoms in CTFs. This work provides a guiding principle for the design of high efficiency photocatalyst structures.
Topics & Concepts
HeteroatomTriazineElectronegativityCovalent bondThiopheneChemistryFuranPhotocatalysisSulfurHydrogenPhotochemistryMaterials scienceOrganic chemistryCatalysisRing (chemistry)Covalent Organic Framework ApplicationsAdvanced Photocatalysis TechniquesCaching and Content Delivery