<i>tert</i> -Butyl hydroperoxide-mediated rapid 30-second oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

Abstract

A novel Au/CeO 2 -catalyzed TBHP system achieves 95% FDCA selectivity at full 5-HMF conversion in 30 s (90 °C), driven by stabilized radicals and van der Waals-enhanced spatial proximity for efficient oxidative activation.

Topics & Concepts