Supramolecular carbohydrate-based hydrogels from oxidative hydroxylation of amphiphilic β-<i>C</i>-glycosylbarbiturates and α-glucosidase-induced hydrogelation
Shun Yao, Robin Brahmi, Anaïs Bouschon, Jing Chen, Sami Halila
Abstract
An ecofriendly two-step synthesis in water enabled the obtention of neutral amphiphilic β- C -glycosylbarbiturates with self-assembly properties capable of supramolecular hydrogelation. And, an α-glucosidase induced sol-to-gel phase transition.
Topics & Concepts
HydroxylationAmphiphileSupramolecular chemistrySelf-healing hydrogelsChemistryOxidative phosphorylationCarbohydrateOrganic chemistryStereochemistryBiochemistryEnzymeMoleculePolymerCopolymerSupramolecular Self-Assembly in MaterialsCarbohydrate Chemistry and SynthesisGlycosylation and Glycoproteins Research