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Practical Considerations in the Design and Use of Non‐Crystalline Metal–Organic Frameworks

Hamidreza Mahdavi, Farnaz Zadehahmadi, Mehran Arzani, Leena Melag, Ashley L. Sutton, Muhammad Sadiq, Zongli Xie, Matthew R. Hill, Benny D. Freeman

2025Advanced Materials10 citationsDOIOpen Access PDF

Abstract

The concept of non-Crystalline Metal-Organic Frameworks (MOFs) is both theoretically exciting and rich in potential applications. Since their conceptual introduction, research in this field has experienced significant growth. This review provides a comprehensive overview of the design, synthesis, and applications of non-crystalline MOFs, highlighting the current state of the art. It examines the fundamental principles of non-crystalline MOFs, the various synthetic approaches, and the nature of non-crystalline MOFs. Additionally, the review outlines their pathway from the laboratory to industrial applications, emphasizing challenges and opportunities for further development.

Topics & Concepts

Metal-organic frameworkNanotechnologyMaterials scienceEngineering ethicsDesign elements and principlesField (mathematics)Systems engineeringBiochemical engineeringEngineeringOrganic chemistryChemistryMathematicsAdsorptionPure mathematicsMetal-Organic Frameworks: Synthesis and ApplicationsBoron and Carbon Nanomaterials ResearchX-ray Diffraction in Crystallography