Visible-light-induced decarboxylation/defluorosilylation protocol for synthesis of<i>gem</i>-difluoroalkenes
Pan Gao, Liping Cui, Guodong Zhang, Feng Chen
Abstract
A catalytic defluorosilylation is disclosed that provides a concise route to gem -difluoroallylsilanes with broad functional-group compatibility from trifluoromethylalkenes and silacarboxylic acids, stable silyl radical precursors.
Topics & Concepts
DecarboxylationSilylationCatalysisChemistryCompatibility (geochemistry)Combinatorial chemistryFunctional groupOrganic chemistryMaterials sciencePolymerComposite materialFluorine in Organic ChemistryRadical Photochemical ReactionsSulfur-Based Synthesis Techniques