Atomically Precise Integration of Multiple Functional Motifs in Catalytic Metal–Organic Frameworks for Highly Efficient Nitrate Electroreduction
Yang Lv, Jian Su, Yuming Gu, Bailin Tian, Jing Ma, Jing‐Lin Zuo, Mengning Ding
Abstract
production. A novel "dynamic ligand dissociation" mechanism provides an unprecedented working principle that allows for the use of a high-quality MOF crystalline structure to function as highly ordered, high-density, single-atom catalyst (SAC)-like catalytic systems and ensures the maximum utilization of the metal centers within the MOF structure. Further, the atomically precise assembly of multiple functional motifs within a MOF catalyst offers an effective and facile strategy for the future development of framework-based enzyme-mimic systems.
Topics & Concepts
CatalysisMetal-organic frameworkElectrochemistryChemistryNitrateElectron transferAmmonia productionRedoxNanotechnologyMaterials scienceChemical engineeringInorganic chemistryPhotochemistryAdsorptionElectrodeOrganic chemistryPhysical chemistryEngineeringAmmonia Synthesis and Nitrogen ReductionMetal-Organic Frameworks: Synthesis and ApplicationsAdvanced Photocatalysis Techniques