Supramolecular hybrids of chiral Waugh polyoxometalate with cyclodextrins
Zhen-Qing Qi, Mingyue Wang, Jia-Chi Shen, You‐Zhao Lan, Zhan‐Guo Jiang, Cai‐Hong Zhan
Abstract
Cyclodextrins promote the homochiral crystallization of Polyoxometalate Λ-{MnMo 9 } enantiomer to isolate two unprecedented supramolecular architectures with enhanced circular dichroism signal.
Topics & Concepts
PolyoxometalateSupramolecular chemistryStackingIsothermal titration calorimetryChirality (physics)Supramolecular chiralityCircular dichroismEnantiomerMaterials scienceCyclodextrinCrystallographyChemistryNanotechnologyStereochemistryCrystal structureCatalysisOrganic chemistryPhysicsChiral symmetry breakingSymmetry breakingPhysical chemistryNambu–Jona-Lasinio modelQuantum mechanicsPolyoxometalates: Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Self-Assembly in Materials