Synthesis of reverse glycosyl fluorides <i>via</i> organophotocatalytic decarboxylative fluorination of uronic acids
Han Ding, Ningjie Yan, Peng Wang, Song Ni, Qikai Sun, Tiantian Li, Ming Li
Abstract
Mes-Acr*-catalyzed decarboxylative fluorination of structurally diverse uronic acids under blue light irradiation provides an alternative avenue for the synthesis of reverse glycosyl fluorides of medicinal and biological relevance.
Topics & Concepts
ChemistryGlycosylUronic acidOrganic chemistryCatalysisCombinatorial chemistryPolysaccharideFluorine in Organic ChemistryCarbohydrate Chemistry and SynthesisRadical Photochemical Reactions