Microwave–Driven Interface Engineering Enhancing Electron Flow for Highly Efficient Solar NO Oxidation over rGO-Integrated NH<sub>2</sub>-MIL125(Ti)/TiO<sub>2</sub>
Xuejian Cheng, Haotong Ma, Rong Yang, Handong Zhang, Wenchao Wang, Yingchun Miao, Shuning Xiao
Abstract
Interface design plays a pivotal role in developing high-performance photocatalysts for NO oxidation. In this work, a hierarchical rGO-integrated NH 2 -MIL125(Ti)/TiO 2 photocatalyst was constructed using a combined liquid-phase and solid-phase microwave synthesis approach. The liquid-phase microwave process enabled the precise deposition of NH 2 -MIL125(Ti) on graphene oxide (GO), forming strong interfacial bonds, while the solid-phase microwave thermal shock (SMTS) transformed GO into rGO and induced the formation of TiO 2 nanoparticles. This hierarchical structure established an efficient electron transport pathway, promoting charge separation and directional electron transfer to activate O 2 and generate superoxide radicals ( • O 2 – ) as the primary reactive species. The resulting photocatalyst achieved remarkable NO oxidation performance, with an 81.2% NO removal efficiency and a NO 3 – selectivity of 98.5% under simulated sunlight. This study highlights the potential of microwave–driven interface engineering in the innovative design of photocatalysts for environmentally sustainable applications.