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Metal-free sulfonylative annulations of alkyl diiodides with sulfur dioxide: synthesis of cyclic aliphatic sulfones

Xiuwen Jia, Chunxi Huang, Xuemei Zhang, Zhong Lian

2021Organic Chemistry Frontiers24 citationsDOI

Abstract

A straightforward protocol for cyclic aliphatic sulfones is effectively established via sulfonylative annulations of alkyl diiodides and gaseous sulfur dioxide. Five- to nine-membered cyclic aliphatic sulfones were afforded in this manner.

Topics & Concepts

ChemistryAlkylSulfurSulfur dioxideMetalOrganic chemistrySulfur-Based Synthesis TechniquesCatalytic C–H Functionalization MethodsRadical Photochemical Reactions
Metal-free sulfonylative annulations of alkyl diiodides with sulfur dioxide: synthesis of cyclic aliphatic sulfones | Litcius