Unimolecular and water reactions of oxygenated and unsaturated Criegee intermediates under atmospheric conditions
Luc Vereecken, Anna Novelli, Astrid Kiendler‐Scharr, Andreas Wahner
Abstract
Theoretical kinetic data is used to update structure–activity relationships for Criegee intermediates, including fast reactions for intramolecular insertion in oxygenated SCI.
Topics & Concepts
ChemistryOzonolysisOzonidePhotochemistryIntramolecular forceReactivity (psychology)Reaction rateSubstituentReaction intermediateReactive intermediateMoietyReaction mechanismComputational chemistryOrganic chemistryCatalysisAlternative medicineMedicinePathologyAtmospheric chemistry and aerosolsAtmospheric Ozone and ClimateCatalytic Processes in Materials Science