Design of a Novel Lead-Free Perovskite Solar Cell for 17.83% Efficiency
Syed Abdul Moiz, Ahmed N. M. Alahmadi, Abdulah Jeza Aljohani
Abstract
Lead halide perovskite solar cell shows an enormous potential for the next generation renewable energy, but it also offers some environmental hazards due to their inherent lead-based toxicity. On the other hand, if lead based perovskite is efficiently replaced by other non-toxic metal based perovskite then their toxicity can remarkably be reduced for photovoltaic applications. In this study, a novel lead free compound Cs <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> TiBr <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">6</sub> based photovoltaic device is proposed as Au/PEDOT:PSS/ Cs <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> TiBr <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">6</sub> /TiO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> /AZO, where each layer is optimized and analysed through a series of simulations for maximum power-conversion efficiency using SCAPS-1D software. Comprehensive optimization of the thickness and doping density of each layer leads to the maximum power-conversion efficiency up to 17.83% for our proposed solar cell. Therefore, we believe that these results will provide a route heading towards the progress of lead-free and highly efficient perovskite photovoltaic devices.