Suppressing Growth Strategy on Synthesizing Stable and High-Quality Blue-Emitting CsPbBr<sub>3</sub> Quantum Dots
Huazheng Li, Gaoling Zhao, Bin Song, Weixia Dong, Gaorong Han
Abstract
In recent years, deep-blue perovskite light-emitting diodes (PeLEDs) based on ultra-small CsPbBr 3 quantum dots (QDs) have attracted increased attention. However, ultra-small CsPbBr 3 QDs tend to have more defects and more nonradiative processes because of their ultrafast nucleation and growth rates. How to suppress the nucleation and growth rate is an important issue for developing deep-blue emitting CsPbBr 3 QDs with high performance. Herein, a modified hot-injection method (MM) is designed for suppressing the growth process of CsPbBr 3 . The ligands of oleic acid (OA) and oleylamine (OAm) are employed instead of octadecene (ODE) as the solution, and as a result, the strong confined and high-quality CsPbBr 3 QDs (∼4.45 nm) are obtained, presenting strong deep-blue emission (≈465 nm) with a photoluminescence quantum yield (PLQY) of 95%, an average lifetime of 8.84 ns, and a large exciton binding energy of 268.7 meV, which can maintain blue emission over 30 days under atmospheric conditions. Compared with the CsPbBr 3 nanocubes (NCs) obtained by the common hot-injection method (CM), the CsPbBr 3 QDs obtained by MM have fewer defects and trap states, resulting in less nonradiative processes. In addition, the fabricated PeLEDs based on the above CsPbBr 3 QDs show deep-blue emission with Commission Internationale de l’Eclairage (CIE) color coordinates of (0.129 and 0.074), which is better than the blue standard of the National Television Standards Committee (NTSC). Evidently, this work provides a way to synthesize ultra-small CsPbBr 3 QDs and also reflects the important influence of the reaction solvent on perovskite synthesis.