Tailoring the π–π stacking interaction among organic cations in hybrid metal halide crystals towards tunable light emission
Qi Zhang, Xinyi Lin, Shanji Guo, Yaqing Zhang, Yan Jiang, Wei Zhang, Hui Li, Yanan Feng, Lingyun Li, Zheyuan Liu, Yan Yu
Abstract
A series of luminescent 23-Cd1−xZnxCl4 (0 ≤ x ≤ 1) crystals are designed and synthesized based on the π–π stacking induced tunable light emission mechanism, which is first revealed in this work.
Topics & Concepts
StackingMaterials scienceHalideLuminescenceMetalLight emissionOptoelectronicsPhotochemistryCrystallographyInorganic chemistryOrganic chemistryMetallurgyChemistryPerovskite Materials and ApplicationsLuminescence and Fluorescent MaterialsLanthanide and Transition Metal Complexes