Deciphering structural evolution of adsorbed ˙OH species on Zr-oxo nodes of UiO-66 to modulate methane hydroxylation
Ling‐Chan Tian, Geqian Fang, Yun Zhou, Wenjun Yu, Lin Li, Jin‐Nian Hu, Haiyan Wang, Jinxia Liang, Chun Zhu, Xiaodong Wang, Jian Lin
Abstract
The ˙OH quantity and DSOM performance on Zr-oxo nodes in the UiO-66-H catalyst exhibit a volcano-like curve relationship due to the evolution of p-band centers of O atoms on adsorbed oxygenic species.
Topics & Concepts
HydroxylationMethaneAdsorptionChemistryChemical engineeringInorganic chemistryPhysical chemistryOrganic chemistryEngineeringEnzymeCatalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsMetal-Organic Frameworks: Synthesis and Applications