Cooperative B–H bond activation: dual site borane activation by redox active κ<sup>2</sup>-<i>N</i>,<i>S</i>-chelated complexes
Mohammad Zafar, Asif Ahmad, Suvam Saha, Rongala Ramalakshmi, Thierry Roisnel, Sundargopal Ghosh
Abstract
-H-H coordination modes. Density functional theory (DFT) calculations suggest that the activation of boranes across the dual Ru-N site is more facile than the Ru-S one.
Topics & Concepts
BoraneChemistryChelationRedoxActive siteStereochemistryMedicinal chemistryInorganic chemistryCatalysisOrganic chemistryOrganoboron and organosilicon chemistryCatalytic Cross-Coupling ReactionsCatalytic C–H Functionalization Methods