Morphology–transport relationships for SBA-15 and KIT-6 ordered mesoporous silicas
Janika Hochstrasser, Artur Svidrytski, Alexandra Höltzel, Tatiana Priamushko, Freddy Kleitz, Wu Wang, Christian Kübel, Ulrich Tallarek
Abstract
= 10.5 nm) silica samples. For λ = 0, the pointlike tracers reproduce the true diffusive tortuosities. For 0 ≤λ < 0.5, the derived hindrance factor quantifies the extent to which diffusion of finite-size tracers through the materials is hindered compared with free diffusion in the bulk liquid. The hindrance factor connects the transport properties of the ordered silicas to their mesopore space morphologies and enables quantitative comparison with random mesoporous silicas. Key feature of the ordered silicas is a narrow, symmetric mesopore size distribution (∼10% relative standard deviation), which engenders a sharper decline of the accessible-porosity window with increasing λ than observed for random silicas with their wide, asymmetric mesopore size distributions. As support structures, ordered mesoporous silicas should offer benefits for applications where spatial confinement effects and molecular size-selectivity are of prime importance. On the other hand, random mesoporous silicas enable higher diffusivities for λ > 0.3, because the larger pores carry most of the diffusive flux and keep pathways open when smaller pores have closed off.