Unconventional Heterobidentate Coordination of 4‐Hydroxypyridine Leading to Remarkably Strong Second‐Harmonic Generation in Zn(C<sub>5</sub>H<sub>4</sub>NO)<sub>2</sub>
Can Yang, Jie Gou, Yaolong Zhu, Yi Xiong, Zece Zhu, Ling Chen, Qi Wu
Abstract
Abstract Herein, we report an unconventional heterobidentate coordination mode of conventional 4‐hydroxypyridine ligand in a novel compound Zn(C 5 H 4 NO) 2 . The strong heterobidentate coordination interactions between Zn 2+ and 4‐hydroxypyridine ligands promote a uniform alignment of the polarization of each [ZnO 2 N 2 ] tetrahedral building unit, resulting in remarkably strong second‐harmonic generation (SHG) with an intensity that is the largest among all UV‐transparent Zn‐containing metal‐organic compounds reaching 13.6×KDP. Moreover, Zn(C 5 H 4 NO) 2 processes a suitable optical band gap of 4.40 eV, high thermal stability up to 300 °C, excellent air stability, and strong water resistance, demonstrating great application potential. Additionally, Zn(C 5 H 4 NO) 2 exhibits photoluminescence with a significantly enhanced lifetime of 558 ms, accompanied by a rare blue afterglow visible to the naked eye, lasting up to 5 s.