Transferring Lithium Ions in the Nanochannels of Flexible Metal–Organic Frameworks Featuring Superchaotropic Metallacarborane Guests: Mechanism of Ionic Conductivity at Atomic Resolution
Jiřı́ Brus, Jiřı́ Czernek, Martina Urbanová, Ján Rohlíček, Tomáš Plecháček
Abstract
through the channel walls. Our findings provide a detailed atomic-resolution insight into the mechanism of ionic conductivity and thus have significant implications for the design of the next generation of energy-related materials.
Topics & Concepts
Materials scienceChemical physicsIonConductivityIonic bondingIonic conductivityLithium (medication)Metal-organic frameworkSolid-state nuclear magnetic resonanceElectrolyteNanotechnologyElectrodePhysical chemistryAdsorptionChemistryNuclear magnetic resonanceOrganic chemistryEndocrinologyPhysicsMedicineAdvanced Battery Materials and TechnologiesAdvanced NMR Techniques and ApplicationsAdvancements in Battery Materials