Experimental proof for σ and π-hole driven dual pnicogen bonding in phosphoryl chloride-nitromethane heterodimers: A combined matrix isolation infrared and ab initio computational studies
Nandalal Mahapatra, Swaroop Chandra, N. Ramanathan, K. Sundararajan
Topics & Concepts
NitromethaneChemistryHydrogen bondMatrix isolationAb initioComputational chemistryAb initio quantum chemistry methodsHalogen bondMoleculeDimerCrystallographyChemical physicsOrganic chemistryCrystallography and molecular interactionsSolid-state spectroscopy and crystallographyCrystal structures of chemical compounds