Photoredox/persistent radical cation dual catalysis for alkoxy radical generation from alcohols
Yanjiao Xiong, Xiaoyi Zhang, Hongmei Guo, Xuesong Wu
Abstract
A mild and general strategy for the direct generation of alkoxy radicals from simple aliphatic alcohols enabled by visible-light-induced photoredox/persistent radical cation dual catalysis is developed.
Topics & Concepts
ChemistryPhotoredox catalysisRadicalAlkoxy groupPhotochemistryCatalysisDual roleDual (grammatical number)Combinatorial chemistryOrganic chemistryPhotocatalysisAlkylArtLiteratureRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization Methods