Gas-phase organometallic catalysis in MFM-300(Sc) provided by switchable dynamic metal sites
Juan L. Obeso, Alfredo López‐Olvera, Catalina V. Flores, Ricardo A. Peralta, Ilich A. Ibarra, Carolina Leyva
Abstract
due to the presence of hemilabile Sc-O bonds. MFM-300(Sc) showed high mechanical and chemical stability, and the crystalline structure was maintained after the catalytic reaction. The catalytic activity of the material was quantified by performing a gas-phase reaction using a continuous flow reactor. The acetone conversion in MFM-300(Sc) was estimated to be 27.7% with no loss of activity after catalytic cycles.
Topics & Concepts
CatalysisAcetoneChemistryMetalGas phasePhase (matter)Physical chemistryOrganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsCatalysis and Hydrodesulfurization StudiesMembrane Separation and Gas Transport