Patterned Cu Nanoparticle Film for All-Cu Interconnection Without Chemical Mechanical Polishing Pretreatment
Shuaiqi Wang, Guisheng Zou, Yongchao Wu, Zhongyang Deng, Rongbao Du, Lei Liu
Abstract
All-Cu interconnects with fine pitch scalability and excellent electrical performance are highly considered the next interconnection node for the coming era of chiplet integration. However, current all-Cu interconnection through Cu–Cu direct bonding relies much on expensive chemical mechanical polishing (CMP) processes to reduce surface roughness to several nanometers. Herein, Cu nanoparticle (CNP) film prepared by pulsed laser deposition (PLD) was successfully patterned into micro bumps of <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$120 \mu \text{m}$ </tex-math></inline-formula> pitch and sintered at 160 °C–250 °C to form all-Cu interconnects without using CMP pretreatment. The fabricated bumps had a low Young’s modulus of only 1 GPa and could produce vertical collapse of several microns in bonding process, providing compliance with surfaces having high roughness and poor coplanarity. The bonded interconnects also exhibited excellent mechanical quality with shear strength <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$>$ </tex-math></inline-formula> 20 MPa at 160 °C, 15 MPa and <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$>$ </tex-math></inline-formula> 90 MPa at 250 °C, 20 MPa, which was superior to most reported Cu–Cu bonding using patterned nanomaterials. Patterning mechanism in PLD process involving incident characteristics of CNP flux, evolution of bump morphology was investigated and bump morphology’s influence on bonding properties was analyzed in detail. The strategy illustrated here could lead to develop a low-temperature, low-pressure assembly technique with less reliance on CMP for all-Cu interconnection.