Reaction pathways and deactivation mechanisms of isostructural Cr and Fe MIL-101 during liquid-phase styrene oxidation by hydrogen peroxide
Rachel A. Yang, Michele L. Sarazen
Abstract
Isostructural MIL-101(Cr, Fe) is investigated as a modular platform to quantify differences in reactivity, selectivity, and deactivation as functions of intrinsic material properties for styrene oxidation by hydrogen peroxide at mild conditions.
Topics & Concepts
IsostructuralHydrogen peroxideStyreneChemistrySelectivityCatalysisReactivity (psychology)PeroxidePhotochemistryInorganic chemistryOrganic chemistryPolymerCopolymerCrystal structurePathologyAlternative medicineMedicineMetal-Organic Frameworks: Synthesis and ApplicationsCatalytic Processes in Materials ScienceAdvanced Photocatalysis Techniques