Slow relaxation of the magnetization, reversible solvent exchange and luminescence in 2D anilato-based frameworks
Samia Benmansour, Antonio Hernández-Paredes, Arpan Mondal, Gustavo López Martínez, Josep Canet‐Ferrer, Sanjit Konar, Carlos J. Gómez‐García
Abstract
O, dimethylformamide (dmf) and dimethylsulfoxide (dmso), can exchange the coordinated and non-coordinated solvent molecules (G) in a reversible way. These multifunctional frameworks show field induced slow relaxation of the magnetization and luminescence that can be easily and reversibly modified by solvent exchange.
Topics & Concepts
SolventLuminescenceRelaxation (psychology)MagnetizationDimethylformamideLigand (biochemistry)MoleculeChemistryPhysical chemistryMaterials scienceChemical physicsOrganic chemistryOptoelectronicsPhysicsMagnetic fieldReceptorQuantum mechanicsPsychologyBiochemistrySocial psychologyMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes