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Preparation and defect structure analysis of near-stoichiometric lithium tantalate wafers

Xuefeng Xiao, Qingyan Xu, Shuaijie Liang, Huan Zhang, Lingling Ma, Lian Hai, Xuefeng Zhang

2022RSC Advances13 citationsDOIOpen Access PDF

Abstract

reaches a maximum, showing that at this Li concentration the NSLT crystal has a more perfect lattice structure. In this study, we propose a mixed defect model in which polarons coexist with Li vacancies and Ta inversion, explaining the change in Ta valence state in lithium tantalate crystals. This model is more in line with the observed results in this work. The new hybrid defect model and the variation law of Ta valence state with Li concentration proposed in this paper provide a new direction and experimental proof for the defect study of NSLT crystals, and also provide a theoretical basis to explore the Li content at the best physical properties of NSLT crystals.

Topics & Concepts

Lithium tantalateStoichiometryLithium (medication)TantalateMaterials scienceWaferAnalytical Chemistry (journal)Physical chemistryChemistryNanotechnologyOptoelectronicsLithium niobateFerroelectricityOrganic chemistryEndocrinologyMedicineDielectricFerroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsMicrowave Dielectric Ceramics Synthesis
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