Topological control of metal–organic frameworks toward highly sensitive and selective detection of chromate and dichromate
Zi‐Jian Li, Yu Ju, Xiaoling Wu, Xiaoyun Li, Jie Qiu, Yongxin Li, Zhi‐Hui Zhang, Ming‐Yang He, Linjuan Zhang, Jian‐Qiang Wang, Jian Lin
Abstract
A synthetic modulation approach has given rise to two topologically distinct thorium-based MOFs, whose polymorphism allows for elucidating how the structure of MOF, in isolation, influences the sensing efficacy of Cr( vi ) oxyanions.
Topics & Concepts
Chromate conversion coatingMetal-organic frameworkThoriumTopology (electrical circuits)Materials scienceNanotechnologyChemistryCombinatorial chemistryPhysical chemistryMathematicsMetallurgyUraniumCoatingCombinatoricsAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsMolecular Sensors and Ion DetectionAdvanced Nanomaterials in Catalysis