Monolayer Kagome metals AV3Sb5
Sun-Woo Kim, Hanbit Oh, Eun-Gook Moon, Youngkuk Kim
Abstract
Abstract Recently, layered kagome metals A V 3 Sb 5 ( A = K, Rb, and Cs) have emerged as a fertile platform for exploring frustrated geometry, correlations, and topology. Here, using first-principles and mean-field calculations, we demonstrate that A V 3 Sb 5 can crystallize in a mono-layered form, revealing a range of properties that render the system unique. Most importantly, the two-dimensional monolayer preserves intrinsically different symmetries from the three-dimensional layered bulk, enforced by stoichiometry. Consequently, the van Hove singularities, logarithmic divergences of the electronic density of states, are enriched, leading to a variety of competing instabilities such as doublets of charge density waves and s - and d -wave superconductivity. We show that the competition between orders can be fine-tuned in the monolayer via electron-filling of the van Hove singularities. Thus, our results suggest the monolayer kagome metal A V 3 Sb 5 as a promising platform for designer quantum phases.