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Hydrogen embrittlement micromechanisms and direct observations of hydrogen transportation by dislocations during deformation in a carbon-doped medium entropy alloy

Donghan Kim, Mohammad Moallemi, Kyung‐Shik Kim, Sung-Joon Kim

2022Journal of Materials Research and Technology18 citationsDOIOpen Access PDF

Abstract

The hydrogen embrittlement micromechanisms and the effect of carbon interstitial on hydrogen distribution were characterized in Fe40Mn40Ni10Cr10 and Fe38Mn41Ni10Cr10C1 medium entropy alloy. Ex-situ microstructural observations revealed that the segregation of carbon on grain boundaries suppresses hydrogen from being trapped in the grain boundaries for carbon-doped alloy before deformation. However, the distribution of hydrogen was similar for both alloys after plastic strain so that the grain boundaries trapped a large fraction of hydrogen during deformation. The fully intergranular fracture mode in the hydrogen affected area of both alloys was explained by the synergy of grain boundary–dislocation reactions and hydrogen-enhanced grain boundary decohesion effects.

Topics & Concepts

Materials scienceHydrogen embrittlementGrain boundaryHydrogenAlloyEmbrittlementMetallurgyDislocationIntergranular fractureTransgranular fractureIntergranular corrosionComposite materialMicrostructureCorrosionOrganic chemistryChemistryHydrogen embrittlement and corrosion behaviors in metalsHigh Entropy Alloys StudiesHigh-Temperature Coating Behaviors
Hydrogen embrittlement micromechanisms and direct observations of hydrogen transportation by dislocations during deformation in a carbon-doped medium entropy alloy | Litcius