Theoretical insight into decatungstate photocatalyzed alkylation of<i>N</i>-tosylimine<i>via</i>hydrogen atom transfer and proton-coupled electron transfer
Ling-Ying Meng, Yujiao Dong, Bo Zhu, Yujie Liang, Zhong‐Min Su, Wei Guan
Abstract
A radical mechanism of photo-mediated decatungstate catalyzed alkylation of N -tosylimine via C–H activation of ether to construct the C(sp 3 )–C(sp 2 ) bond has been theoretically disclosed.
Topics & Concepts
ChemistryPhotochemistryProton-coupled electron transferHydrogen atomElectron transferImineHydrogen bondQuenching (fluorescence)Density functional theoryEtherComputational chemistryMoleculeFluorescenceCatalysisOrganic chemistryAlkylPhysicsQuantum mechanicsPolyoxometalates: Synthesis and ApplicationsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization Methods