Biomass Based N/O Codoped Porous Carbons with Abundant Ultramicropores for Highly Selective CO2 Adsorption
Congxiu Guo, Ya Sun, Hongyan Ren, Bing Wang, Xili Tong, Xuhui Wang, Yu Niu, Jiao Wu
Abstract
In this work, N/O codoped porous carbons (NOPCs) were derived from corn silk accompanied by Na2CO3 activation. The porous structures and surface chemical features of as-prepared carbon materials were tailored by adjusting the Na2CO3 mass ratio. After activation, the optimized sample (NOPC1) with abundant ultramicropores and pyrrolic N displays an enhanced CO2 adsorption capacity of 3.15 mmol g−1 and 1.95 mmol g−1 at 273 K and 298 K at 1 bar, respectively. Moreover, this sample also exhibited high IAST selectivity (16.9) and Henry’s law selectivity (15.6) for CO2/N2 at 298 K as well as moderate heat adsorption. Significantly, the joint effect between ultramicropore structure and pyrrolic N content was found to govern the CO2 adsorption performance of NOPCs samples.